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2. Brad Pitt & Angelina Jolie
You couldn’t have a ‘most charitable’ list without including this dynamic duo. The Jolie-Pitts have been involved in charity work both separately and together, adopting children from devastated nations, taking on rolls as UN ambassadors, and building educational and medical facilities and naming them after their children. Angelina was just recently speaking at the UN about Italy turning refugee boats around, and they help out at home too where they have worked for numerous charities including those to help victims of Hurricane Katrina.